Chemical and Materials Engineering(CEASE PUBLICATION) Vol. 1(4), pp. 111 - 115
DOI: 10.13189/cme.2013.010402
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Kinetic Study on 1,10-Phenantroline Reaction with Cis-[Pt(p-FC₆H₄)₂(SMe₂)₂] Complex

Alireza Akbari ^*, Ali Samie
Department of Chemistry, Payame Noor University, 19395-4697 Tehran, Iran

ABSTRACT

To determine the rate constants and kinetic parameters on the reaction between 1 10-Phenantroline, as a bidentate ligand and cis-[Pt(p-FC₆H₄)₂(SMe₂)₂] complex in acetone and benzene solvents, the reactions were monitored by UV-Vis spectrophotometer. The pseudo-first-order rate constants (kobs=k₁+k₂[phen]) of the reaction were derived, and the values of the first and second order rate constants (k₁ and k₂) calculated using standard equations. The reactions were carried out in the range of 20 to 50℃ The second-order rate constant dependency on the temperature was in agreement with the Arrhenius equation, providing the relevant plots to calculate the activation energy of all the reactions. The ΔH^#(KJ.mol^-1) and ΔS^#(J.mol^-1.K^-1) were obtained 28.677 and –165.9 respectively in benzene. These values were 56.723 and -72.2 respectively, in acetone. The product synthesizing was confirmed using elemental (CHN) and spectral (IR) analysis.

KEYWORDS
Pt(II) Complex, Substitution, UV-Vis Spectrophotometry, Activation Parameters, Kinetics

Cite This Paper in IEEE or APA Citation Styles
(a). IEEE Format:
[1] Alireza Akbari , Ali Samie , "Kinetic Study on 1,10-Phenantroline Reaction with Cis-[Pt(p-FC₆H₄)₂(SMe₂)₂] Complex," Chemical and Materials Engineering(CEASE PUBLICATION), Vol. 1, No. 4, pp. 111 - 115, 2013. DOI: 10.13189/cme.2013.010402.

(b). APA Format:
Alireza Akbari , Ali Samie (2013). Kinetic Study on 1,10-Phenantroline Reaction with Cis-[Pt(p-FC₆H₄)₂(SMe₂)₂] Complex. Chemical and Materials Engineering(CEASE PUBLICATION), 1(4), 111 - 115. DOI: 10.13189/cme.2013.010402.