Journals Information
Universal Journal of Chemistry(CEASE PUBLICATION) Vol. 1(3), pp. 113 - 120
DOI: 10.13189/ujc.2013.010306
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The Electrophilic Substitution of Sydnones: the Reaction with 3-Aryl-4-Phenylsydnones, 3-Arylmethylsydnones and 3-Phenylethylsydnone
Mei-Fang Ding, Kai-Feng Cheng, Ying-Nan Chen, Shaw-Tao Lin*
Department of Applied Chemistry, Providence University, 200, Section 7, Taiwan Boulevard, Sha-Lu District, Taichung, Taiwan, 43301
ABSTRACT
The electrophilic substitution of 3-aryl-4- phenylsydnones, 3-arylmethylsydnones and 3-phenylethyl- sydnone are studied in order to understand extend of dual nature of the sydnone ring. In the reaction, the nitronium cation is more reactive toward to the aryl ring attached at N(3). The presence of a methyl or methoxyl group on the benzene ring of the arylalkyl group or of methylene between the aryl and the sydnonyl ring causes the phenyl ring to become electrophilic.
KEYWORDS
Arylsydnones, Diaryldysnone, Dual Properties, Electrophiles, Nitration
Cite This Paper in IEEE or APA Citation Styles
(a). IEEE Format:
[1] Mei-Fang Ding , Kai-Feng Cheng , Ying-Nan Chen , Shaw-Tao Lin , "The Electrophilic Substitution of Sydnones: the Reaction with 3-Aryl-4-Phenylsydnones, 3-Arylmethylsydnones and 3-Phenylethylsydnone," Universal Journal of Chemistry(CEASE PUBLICATION), Vol. 1, No. 3, pp. 113 - 120, 2013. DOI: 10.13189/ujc.2013.010306.
(b). APA Format:
Mei-Fang Ding , Kai-Feng Cheng , Ying-Nan Chen , Shaw-Tao Lin (2013). The Electrophilic Substitution of Sydnones: the Reaction with 3-Aryl-4-Phenylsydnones, 3-Arylmethylsydnones and 3-Phenylethylsydnone. Universal Journal of Chemistry(CEASE PUBLICATION), 1(3), 113 - 120. DOI: 10.13189/ujc.2013.010306.