Universal Journal of Chemistry(CEASE PUBLICATION) Vol. 1(3), pp. 77 - 84
DOI: 10.13189/ujc.2013.010301
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On the Influence of the Energy Field of the Pores in Solid on Its Filling with Gases and Peculiarities in the Condensation Process

A.G. Zakharov^*
Im Neuwerk 5, 21680 Stade, Germany

ABSTRACT

In the work is investigated the totality of processes when gas filling the pore in solids taking into account the availability of energy fields, which have a decisive influence on the ingress of gas molecules inside the pores. Dependence of filling the pores of the parameters characterizing the energy field is obtained, and shows the presence on it of the extremes, that makes more understandable ways of selecting porous bodies with the desired adsorption capacity in relation to this gas. It is shown that the density of the gas in the pore can be, depending on its radius, smaller and significantly exceeds the density of the gas in the outer scope. Where obtained the isotherms of filling the single pore with gas, taking into account the possibility of condensation in the internal volume, and therefore, having all of the elements, often observed in experimental dependencies. Is studied the influence of the energy field of the pores on the form isotherms filling and parameters of the condensation transition, and shown that it can both facilitate and impede the process of condensation in the pore, i.e. to shift its beginning as in the area of lower and higher external pressures.

KEYWORDS
Pore, Energy Field, Gas Filling, Condensation in Pore

Cite This Paper in IEEE or APA Citation Styles
(a). IEEE Format:
[1] A.G. Zakharov , "On the Influence of the Energy Field of the Pores in Solid on Its Filling with Gases and Peculiarities in the Condensation Process," Universal Journal of Chemistry(CEASE PUBLICATION), Vol. 1, No. 3, pp. 77 - 84, 2013. DOI: 10.13189/ujc.2013.010301.

(b). APA Format:
A.G. Zakharov (2013). On the Influence of the Energy Field of the Pores in Solid on Its Filling with Gases and Peculiarities in the Condensation Process. Universal Journal of Chemistry(CEASE PUBLICATION), 1(3), 77 - 84. DOI: 10.13189/ujc.2013.010301.