Manufacturing Science and Technology Vol. 3(5), pp. 236 - 239
DOI: 10.13189/mst.2015.030507
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Effects of Blending Sequence on Morphology and Mechanical Properties of Polypropylene/Ethylene-octene Copolymer/Clay Nanocomposites


Sedigheh Bagheri Kazemabad 1,*, Alireza Khavandi 1, Daniel Fox 2, Yanhui Chen 2, Hongzhou Zhang 2, Biqiong Chen 3
1 School of Metallurgy and Materials Engineering, Iran University of Science and Technology (IUST), Iran
2 School of Physics and CRANN, Trinity College Dublin, College Green, Ireland
3 Department of Materials Science and Engineering, University of Sheffield, U.K.

ABSTRACT

The objective of this study was to investigate the effects of three blending sequences on morphology and properties of the ternary nanocomposite of polypropylene (PP)/ethylene–octene copolymer (EOC)/clay with double compatibilizers of maleated PP (PP-g-MA) and maleated EOC (EOC-g-MA) prepared by twin-screw extrusion. The X-ray diffraction results in conjuction with transmission electron microscopy images indicated the mixture of exfoliated and intercalated structures possessed by the nanocomposite prepared by simultaneous addition of the ingredients. The nanocomposite in which clay was first mixed with PP and EOC-g-MA and then with EOC and PP-g-MA showed the same morphology. However, in the nanocomposite when clay was first mixed with PP and PP-g-MA and then mixed with EOC and EOC-g-MA, an intercalated structure was observed. The results of mechanical testing showed that there was no significant difference in the yield strength, tensile modulus and flexural modulus among the three nanocomposites. However, the Charpy impact strength of the nanocomposite prepared by simultaneous addition of ingredients was higher than that of the nanocomposites prepared in two mixing steps because of the presence of more organoclay inside the EOC phase in the former.

KEYWORDS
Polypropylene, Clay, Nanocomposite, Blending Sequence

Cite this paper
Sedigheh Bagheri Kazemabad , Alireza Khavandi , Daniel Fox , Yanhui Chen , Hongzhou Zhang , Biqiong Chen . "Effects of Blending Sequence on Morphology and Mechanical Properties of Polypropylene/Ethylene-octene Copolymer/Clay Nanocomposites." Manufacturing Science and Technology 3.5 (2015) 236 - 239. doi: 10.13189/mst.2015.030507.